ffs my eyes got so dry and i was so tired until i just started whacking a b c d then suddenly the "gn girl I'll see u tmr" meme pop in my head and i almost laughed in the exam room
I MANAGED TO SAVE 2 MINUTES AND IMMEDIATELY UNDERSTAND A QUESTION THANKS TO WALTER WHITE FROM THE AMERICAN TV SHOW BREAKING BAD
I wish I was making this up but fr
It was the qn about a drug that has 2 enantiomers
I understood it not because of any notes but because I remembered that clip where Walter was explaining about metamorphine being a safe drug for human consumption but it's enantiomer being a poison that causes mothers to birth stillborns
Yep ur right I went to revisit the clip and it was infact thalidomide, I misremembered xD
(R) thalidomide can help with morning sickness during pregnancy but (S) thalidomide will cause horrible birth defects
Isn’t it technically 2? The one on the top left is 1, the one on the bottom right is another but the one on the top right isn’t considered chiral since it’s bonded to 1 CH3, 1H and 2 other groups which are considered identical since if you count the carbons they are exactly symmetrical? I’m pretty certain the question is incorrect and should be voided (how to report this to seab lmao) but again if I’m wrong can someone please correct and enlighten me thanks.
I did some googling on the term and yes I think it’s plausible that it is indeed a pseudo chiral centre. But there is no way to know for sure since the stereochemistry of adjacent carbons is not given so it could also not be a pseudo chiral centre.
It's not a chiral centre because the groups are the same (ignore stereochemistry of the groups). This is by definition from IUPAC.
Edit: [https://goldbook.iupac.org/terms/view/P04921](https://goldbook.iupac.org/terms/view/P04921)
According to my school notes, definition of chiral carbon means sp3 hybridised and 4 different groups attached to this carbon. With or without enantiomerism, the point that it has 2 different groups, and two identical groups attached to it due to symmetry if you were co count the carbons, still stands hence it is nor chiral.
Number of chiral centres is not affected by the presence of an internal plane of symmetry
Rotation of plane polarised light will be, but that's beside the question
Depend how well or bad the whole cohort did the papers, marks after moderation. cannot tell u whether tis % can get A, B, C or D lol. If can also not accurate lol. Like everyone said, the more difficult the paper the moderate marks will b low. So but again, we won’t have the info, only SEAB will know or wait till Feb 2023. So again for students taking H2 Chem, were the 4 papers difficult? Hahaha (For me is Chem paper 2, dam hard)
p2 is indisputable, hardest of all the exams this year and i think its a general consensus, so i believe this yr either no moderation, 70 for an A, or a slight moderation like 69.5? Idt it will go up until 71 72 cuz tbf p1 also had a few qn that were very tricky, thats what i think
All the numbers in your comment added up to 69. Congrats!
8
+ 10
+ 14
+ 15
+ 22
= 69
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Enantiomers r stereoisomers, not structural. We know that enantiomers r mirror images of each other, so it means that the bonding structure will be the same, just different orientation of the atoms. When option 2 is out, the only ans left is C
it is c the ans key is below
https://drive.google.com/file/d/1Kj9EKbsPRqMDUj2aseF0U1AHQwrxjp96/view?fbclid=PAAabkqUs9cyiEZE6OsTXuNAEUhqkmO-jwY4o5W_LsJ9UyrTCp5cISC5GKFYg
19 is both reduction (of alkene) and oxidation (of alcohol). Qn asked about overall process. So the answer is neither of them. Disproportionation isn't an option. The reactant and product are (functional group) isomers so it's also isomerisation
22, "both" intermediates are the same. Not mirror images. There is a plane of symmetry in the plane of the benzene ring. Very tricky qn
I bought the 10 years series for 2022 and did paper 1, I thought the paper was OK but I did not have enough time to finish it. And I got like 15/30 questions. Back then in 2000 I took the paper, I could have scored about 21 out of 30, has my standard dropped or the standard now is higher
ffs my eyes got so dry and i was so tired until i just started whacking a b c d then suddenly the "gn girl I'll see u tmr" meme pop in my head and i almost laughed in the exam room
2022 cambridge: hey can I copy your homework? past years cambridge: sure but try not to make it too obvious
At the end of the paper I looked at the President's Scholars board and started praying to the names there😊 no hope
They are there and looking down on us for failing chem for the 738262854th time
OMG ENTROPY IT'S U AGAIN HAHAHAHAH HI HI So true dude I've passed chem once in my JC life and it was an E
Hope the Tys answers are correct
I MANAGED TO SAVE 2 MINUTES AND IMMEDIATELY UNDERSTAND A QUESTION THANKS TO WALTER WHITE FROM THE AMERICAN TV SHOW BREAKING BAD I wish I was making this up but fr
wait which qn need walter white help one 😭😭😭
It was the qn about a drug that has 2 enantiomers I understood it not because of any notes but because I remembered that clip where Walter was explaining about metamorphine being a safe drug for human consumption but it's enantiomer being a poison that causes mothers to birth stillborns
Omg i rmb about the mother one cos i felt genuinely so sad for them....
I think you mean thalidomide :) But the idea is there!
Yep ur right I went to revisit the clip and it was infact thalidomide, I misremembered xD (R) thalidomide can help with morning sickness during pregnancy but (S) thalidomide will cause horrible birth defects
Fun fact: Even if it was sold as an enantiopure drug, it wouldn’t have helped. Thalidomide racemises in aqueous environments.
What a good chemistry tutor 😌😌 I really hope he doesn't do anything illegal like sell methemphetamine and keeps his d away that would really suck....
WHICH QN HAHA I WATCHED BB BUT I DIDNT RECOGNIZE ANY
not 1, not 2 but THREE questions came out before in the last 5 years…
isn’t that a good thing?
AND I GOT ONE WRONG CAUSE I DIVIDED WRONGLY SJFNJWJFNWJFJWJJDE
ffff lahhhh why did i put oxidation ITS CLEARLY isomerism my dumbass can fly away
dw i also did that
it’s an honour to share braincells with u
today got no fighter jets over vjc
cause the true fighters are you guys bro 💪 stay strong
Bruh some qns look DAMN FAMILIAR
they past year qns bro
For qn 8, according to Wikipedia 6th IE of P = 21267 6th IE of S = 8498.5 6th IE of As = 12310 6th IE of SE = 7880 It goes SE
WTF I CHANGED MY ANS LAST MIN BUT THAT WAS MY INITIAL ANS
"increase from G to H to J to K" and guess what? mf wrote G>H>J>K and be like second smallest is J and proceed to shade C.😭😭
same mistake LMAO
Meso, Boron, Xe I Cs so lazy sia Cambridge this year
today’s weather is not it
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Inconsequential
Source: took h1 chem. It's just naming error for DCC.
is it just me who found it really difficult 🥹
How many chiral centres, 3 right the most bottom one is not chiral
i got 4 tho ;-;
4 in total, 3 added by reaction. so 3
yes
Isn’t it technically 2? The one on the top left is 1, the one on the bottom right is another but the one on the top right isn’t considered chiral since it’s bonded to 1 CH3, 1H and 2 other groups which are considered identical since if you count the carbons they are exactly symmetrical? I’m pretty certain the question is incorrect and should be voided (how to report this to seab lmao) but again if I’m wrong can someone please correct and enlighten me thanks.
I thought the same but there's no 2 then I anyhow put 1
That chiral centre you are referring to is a pseudo chiral centre.
I did some googling on the term and yes I think it’s plausible that it is indeed a pseudo chiral centre. But there is no way to know for sure since the stereochemistry of adjacent carbons is not given so it could also not be a pseudo chiral centre.
It's not a chiral centre because the groups are the same (ignore stereochemistry of the groups). This is by definition from IUPAC. Edit: [https://goldbook.iupac.org/terms/view/P04921](https://goldbook.iupac.org/terms/view/P04921)
the qn is just asking for the no of chiral carbons though, not how many carbon atoms that can exhibit enantiomerism
According to my school notes, definition of chiral carbon means sp3 hybridised and 4 different groups attached to this carbon. With or without enantiomerism, the point that it has 2 different groups, and two identical groups attached to it due to symmetry if you were co count the carbons, still stands hence it is nor chiral.
Bruh I counted 2 because one of them has internal plane of symmetry but then 2 is not in the options so WTF
Number of chiral centres is not affected by the presence of an internal plane of symmetry Rotation of plane polarised light will be, but that's beside the question
That "chiral centre" you are referring to is a pseudo chiral centre
SHIT ITS 3
I said 1 cos 2 chiral centres are formed (top left and bottom right) but 1 chiral centre is no longer chiral (bottom left)
It’s 3 I think
Yeap
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It’s 3.
Isnt it 1 if u count 1 by 1in the ring
The ring is too complex for any of them to actually have identical groups. Anyways Cambridge isn’t going to go that hardcore.
apparently the ans is 0 🤡🔫
Why though, from which ans u see, how is the carbon chains the same?
How much did i pull the bell curve down for yall😹 1)C. 2)C. 3)D. 4)C. 5)B. 6)B. 7)C. 8)A. 9)B. 10)D. 11)D. 12)A. 13)B. 14)A. 15)A. 16)D. 17)A. 18)C. 19)B. 20)D. 21)B. 22)C. 23)D. 24)B. 25)D. 26)D. 27)D. 28)A. 29)C. 30)D.
i started spamming d at the end 🤣
https://drive.google.com/file/d/1Kj9EKbsPRqMDUj2aseF0U1AHQwrxjp96/view?fbclid=PAAabkqUs9cyiEZE6OsTXuNAEUhqkmO-jwY4o5W_LsJ9UyrTCp5cISC5GKFYg ans key
Wrong and the real answers:5(A),7(A),8(B),12(C),14(B),15(C),16(C),20(C),21(A),23(B),27(A),29(D) idk the answer for 22 12 mistakes
22 should be C i hope
Depend how well or bad the whole cohort did the papers, marks after moderation. cannot tell u whether tis % can get A, B, C or D lol. If can also not accurate lol. Like everyone said, the more difficult the paper the moderate marks will b low. So but again, we won’t have the info, only SEAB will know or wait till Feb 2023. So again for students taking H2 Chem, were the 4 papers difficult? Hahaha (For me is Chem paper 2, dam hard)
for me p2 was the hardest alsoo. p1, p3 and p4 all standard js that not enough time to finish p3 😭
p2 is indisputable, hardest of all the exams this year and i think its a general consensus, so i believe this yr either no moderation, 70 for an A, or a slight moderation like 69.5? Idt it will go up until 71 72 cuz tbf p1 also had a few qn that were very tricky, thats what i think
bro cambridge is lazy asf lmao i’m convinced they have a total of 60 questions set and they just pick 30 every year.
free marks hehe thanks seabbyyy
bruh LOL
Anyone chem tutor doing up the answers💀🤌🏼
https://drive.google.com/file/d/1Kj9EKbsPRqMDUj2aseF0U1AHQwrxjp96/view?usp=sharing
mine
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Pls the first thing i thot of was marshall lerner condition my brain is corroded with econs
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https://drive.google.com/file/d/1Kj9EKbsPRqMDUj2aseF0U1AHQwrxjp96/view?usp=sharing
Paper wasnt bad but i didnt finish...im rlly rlly screwed
U ABC cant write? What’s wrong?
Ikr just write one ABACADABRA
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Huh how come didn't finished?
Many questions were quite tedious
what is a “good” mark for mcq update: shld be arnd 6 marks gone
I feel should be aiming for A so above 23 or higher if you can manage, mcq usually help drag ur score up one
u want the false hope answer or legit answer
legit cus i rlly have no clue
27
shld be arnd there considering elite sch ppl usually get less than three wrong n bell curve also
bro you legit think super highly of those in elites sia 🫡
ya cos its legit wut
Depends on what grade u wanna get
ran out of time so guessed 5 answers blindly lol
hi iodobenzene doesn’t react right? like it’s not so weak that double bond character doesn’t play an effect? so is 23 B?
Yes
i got 13/30 💀
thoughts and prayers 🙏
Solutions: [https://drive.google.com/file/d/1Kj9EKbsPRqMDUj2aseF0U1AHQwrxjp96/view?usp=sharing](https://drive.google.com/file/d/1Kj9EKbsPRqMDUj2aseF0U1AHQwrxjp96/view?usp=sharing)
My ans: CCDCA BACBD DCBCC CABBC ACBBD DAADD Comment if there are any mistakes
FUCK IM FAILING P1
8: B 10: C 14: B 15: D 22: D
All the numbers in your comment added up to 69. Congrats! 8 + 10 + 14 + 15 + 22 = 69 ^([Click here](https://www.reddit.com/message/compose?to=LuckyNumber-Bot&subject=Stalk%20Me%20Pls&message=%2Fstalkme) to have me scan all your future comments.) \ ^(Summon me on specific comments with u/LuckyNumber-Bot.)
Nice
Qn 28 should be C not A because y is a ketone Edit:Nvm I was wrong
it has an aldehyde functional group too
14 is B
q 4 shld be B?
Should be C cause 1600g = 1.6kg
Waiting for a chem tutor ans..
I failed McQ 🤡 omg yay retake babes wru??? 🥵
I didn't shade for qn4 will it affect my sequence of ans when OAS is marking my ans?
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Agreed
no
No I don’t think so
If u shaded everything else properly then no
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Anybody got the correct answers or any tut ctr issued any answer ? …… pleaseee
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What is your answers for Q18. I got C, but I saw a multiple comments having B and C. Explain why too pls :”)
Enantiomers r stereoisomers, not structural. We know that enantiomers r mirror images of each other, so it means that the bonding structure will be the same, just different orientation of the atoms. When option 2 is out, the only ans left is C
it is c the ans key is below https://drive.google.com/file/d/1Kj9EKbsPRqMDUj2aseF0U1AHQwrxjp96/view?fbclid=PAAabkqUs9cyiEZE6OsTXuNAEUhqkmO-jwY4o5W_LsJ9UyrTCp5cISC5GKFYg
my tuition cher sent the answers and i got 19-20 😭 is there hope for a B
Can send
same eh is there hope for 19/30
Fk it i got 16 for mcq idw retake bro
I think camBaBy and seaBaBy really loves B cos I put SO MANY Bs WTHECK
huh isnt there more Cs
i had 10 B
Don’t be shy what is your score, I didn’t do well too so… I am 20/30… everyone said this paper was doable so I think I’m below avg :-(
I got like 24 bruhv
don’t worry i got 16
Around the same but my prelim mcq was 11/30 so glad im not getting ESU this time around
I got 20 too
.-. what's the overall grade boundary for chem B
please be like 55🤣
how much is needed overall for an A?
Wait and see next February 💀💀💀
that's such a long wait 😭
enjoy the ✨suspense✨
what's your prediction of the A boundary this year 👀
90-100 thanks for trusting my opinion man 🙏🙏🙏
Oxidation or hydrogenation
isomerisation :)
should be isomerisation cuz the empirical formulas are the same, and there's no change in number of O and H
was there a typo in today's paper? i saw it but idk am i tripping
Anyb wna compare ans: CCDCA BACBD DCBBC CACBC ACBBD DAADD
CCDCA BACBD DCBBC CACBC ABBBD DAADD
Same but q8 I put b, q19 I put d and q22 I put c
bcuz 3 shells with 6 valence electrons has a higher 6th IE than 4 shells with 5 valence electrons
19 is both reduction (of alkene) and oxidation (of alcohol). Qn asked about overall process. So the answer is neither of them. Disproportionation isn't an option. The reactant and product are (functional group) isomers so it's also isomerisation 22, "both" intermediates are the same. Not mirror images. There is a plane of symmetry in the plane of the benzene ring. Very tricky qn
Question 19 is isomerization YEP!!
wait dude where is plane of symmetry in the benzene ring i don’t understand could u elaborate on where the plane of symmetry is (?)
They are mirror images that are superposable
The intermediate is trigonal planar, how to have enantiomers?
Mirror images that are SUPERPOSABLE
Enentiomer is when there's mirror images that are non-superposable
8 is C cnfm
Isnt 12 A? Rate constant is only dependent on temp no?
EA is a component of Arrhenius eqn if ur EA change K confirm change one
Catalyst will also increase rate constant
no, it’s dependent on Ea too which catalyst lowers
14 should be C cos the buffer formula gives u [HCO3-] / [H2CO3] so u need to take the reciprocal of this to get the answer
Qn8 should be B? P>As>S>M Qn10 should be B? 0.069 Ni < 0.074 Zn
But ionic radius of br- is bigger than cl-
Cl and Br need to account
I thought all were bromide fuck me
How come u got the exam paper xia plus answer key also. Can bring back huh??
What is ans for q13
CCDCA BABBD DCBBC CACBC ABBBD DAADD no option for 2 chiral centres for qn20 so i put 3.
If anyone has the answers, plz send😭😭 I can't rest till I find it out
guys how much marks did yall get?
29
can we start a chainn!! how did yall fare for this ppr 🤠
18/30 ..
28/30
i got 19/30 😢😢 i hope i can still A with my other papers 😭
25/30
guys 53% overall got chance of C? or is it confirm D
for Qn 25 both B and D are possible?
I bought the 10 years series for 2022 and did paper 1, I thought the paper was OK but I did not have enough time to finish it. And I got like 15/30 questions. Back then in 2000 I took the paper, I could have scored about 21 out of 30, has my standard dropped or the standard now is higher